A vitreous Kr·2SiO2 | Nature
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ABSTRACT THERE are many studies1–7 of the presence of inert gases in glasses. Because they have no electron affinity and high ionisation potentials (12 eV for Xe to 24 eV for He) the
solubility of inert gases in glasses has been considered a simple physical process with no strong chemical interaction within the glass network. Recent work on pressure dependence of inert
gas in vitreous1 and crystalline2 silica (SiO2) showed that the equilibrium solubility may be explained qualitatively by a statistical thermodynamic model3. At non-equilibrium conditions,
however, a large quantity of inert gases can be incorporated into SiO2 by processes such as glow discharge8,9 and sputtering10,11, and here, the amount of inert gases in SiO2 far exceeds the
equilibrium solubility. Using a high-rate sputtering technique, we prepared a SiO2 deposit containing 16.1 at. % Kr, expressed by a glass formula, Kr·2SiO2 and we report here the unique
characteristics of this material. Access through your institution Buy or subscribe This is a preview of subscription content, access via your institution ACCESS OPTIONS Access through your
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FAQs * Contact customer support SIMILAR CONTENT BEING VIEWED BY OTHERS HOT DENSE SILICA GLASS WITH ULTRAHIGH ELASTIC MODULI Article Open access 17 August 2022 PHASE SEPARATION IN
MULLITE-COMPOSITION GLASS Article Open access 21 October 2022 REVISITING LEBEDEV’S ONE-CENTURY OLD EXPERIMENT Article Open access 31 July 2022 REFERENCES * Shelby, J. E. _J. appl. Phys._ 47,
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of Elements_ ch. 2, 27 (John Wiley, New York, 1974). Google Scholar Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Materials Department, Battelle Pacific Northwest
Laboratory, Richland, Washington, 99352 RONG WANG Authors * RONG WANG View author publications You can also search for this author inPubMed Google Scholar RIGHTS AND PERMISSIONS Reprints and
permissions ABOUT THIS ARTICLE CITE THIS ARTICLE WANG, R. A vitreous Kr·2SiO2. _Nature_ 270, 705–706 (1977). https://doi.org/10.1038/270705a0 Download citation * Received: 14 September 1977
* Accepted: 25 October 1977 * Published: 01 December 1977 * Issue Date: 22 December 1977 * DOI: https://doi.org/10.1038/270705a0 SHARE THIS ARTICLE Anyone you share the following link with
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