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ABSTRACT This review article concerns with the syntheses of polyrotaxanes and polyrotaxane networks that can be constructed mainly on the basis of the concept of dynamic covalent bond

chemistry. At the beginning of the review, synthetic methods of rotaxanes are briefly summarized along with several high yielding preparations. Synthesis of poly[3]rotaxane by the reaction

of homoditopic monomers utilizing the thiol-disulfide interchange reaction was discussed in detail, among polyrotaxanes possessing topological bonds for the monomer linking in the main

chain. Polyrotaxane network was prepared by a similar protocol from a polyfunctional crown ether and a dumbbell-shaped homoditopic axle containing two _sec_-ammonium salt moieties and

centrally located disulfide bond. Some characteristics of the polyrotaxane network were demonstrated, including the recyclable property as the crosslinked polymer. The meaning and

applicability of the reversible crosslinking/decrosslinking system developed in the polyrotaxane network are specially emphasized for unique and potential application. SIMILAR CONTENT BEING

VIEWED BY OTHERS PRECISE SYNTHESIS OF POLYROTAXANE AND PREPARATION OF SUPRAMOLECULAR MATERIALS BASED ON ITS MOBILITY Article 12 January 2021 AN APPROACH TO MOFAXANES BY THREADING ULTRALONG

POLYMERS THROUGH METAL–ORGANIC FRAMEWORK MICROCRYSTALS Article Open access 09 June 2023 A RATIONAL ENTRY TO CYCLIC POLYMERS VIA SPONTANEOUS AND SELECTIVE CYCLIZATION REACTIONS Article 19

October 2020 ARTICLE PDF REFERENCES * J.-P. Sauvage and C. Dietrich-Buchecker, “Molecular Catenanes, Rotaxanes, and Knots,” Wiley-VCH, New York, Weinheim, 1999. * D. B. Amabilino and J. F.

Stoddart, _Chem. Rev._, 95, 2725 (1995). * T. Takata and N. Kihara, _Rev. Heteroatom Chem._, 22, 197 (2000). * N. Kihara and T. Takata, _Yukigosei Kagaku Kyokaishi_, 59, 206 (2001). * H. W.

Gibson, M. C. Bheda, and P. T. Engen, _Prog. Polym. Sci._, 19, 843 (1994). * F. M. Raymo and J. F. Stoddart, _Chem. Rev._, 99, 1643 (1999). * A. Harada, _Acta Polym._, 49, 3 (1998). * T.

Takata, N. Kihara, and Y. Furusho, _Adv. Polym. Sci._, 171, 1 (2004). * A. G. Kolchinski, D. H. Busch, and N. W. Alcock, _J. Chem. Soc., Chem. Commun._, 1289 (1995). * P. R. Ashton, E. J. T.

Chrystal, P. T. Glink, S. Menzer, C. Schuavo, N. Spencer, J. F. Stoddart, P. A. Tasker, A. J. P. White, and D. J. Williams, _Chem. Eur. J._, 2, 709 (1996). * H. Kawasaki, N. Kihara, and T.

Takata, _Chem. Lett._, 10, 1015 (1999). * N. Kihara, N. Nakakoji, and T. Takata, _Chem. Lett._, 924 (2002). * A. G. Kolchinski, N. W. Alcock, R. A. Roesner, and D. H. Busch, _Chem. Commun._,

1437 (1998). * N. Kihara, J.-I. Shin, Y. Ohga, and T. Takata, _Chem. Lett._, 6, 592 (2001). * P. R. Ashton, P. T. Glink, J. F. Stoddart, S. Menzer, P. A. Tasker, A. J. P. White, and D. J.

Williams, _Tetrahedron Lett._, 37, 6217 (1996). * P. R. Ashton, P. T. Glink, J. F. Stoddart, P. A. Tasker, A. J. P. White, and D. J. Williams, _Chem. Eur. J._, 2, 729 (1996). * N. Watanabe,

T. Yagi, N. Kihara, and T. Takata, _Chem. Commun._, 2720 (2002). * T. Takata, H. Kawasaki, S. Asai, N. Kihara, and Y. Furusho, _Chem. Lett._, 2, 111 (2000). * T. Takata, H. Kawasaki, N.

Kihara, and T. Furusho, _Macromolecules_, 34, 5449 (2001). * S. J. Rowan, S. J. Cantrill, G. R. L. Cousins, J. K. M. Sanders, and J. F. Stodddart, _Angew. Chem. Int. Ed._, 41, 898 (2002). *

S. J. Rowan, S. J. Cantrill, and J. F. Stoddart, _Org. Lett._, 1, 129 (1999). * S. J. Rowan and J. F. Stoddart, _J. Am. Chem. Soc._, 122, 164 (2000). * Y. Furusho, T. Hasegawa, A. Tsuboi, N.

Kihara, and T. Takata, _Chem. Lett._, 1, 18 (2000). * Y. Furusho, T. Oku, T. Hasegawa, A. Tsuboi, N. Kihara, and T. Takata, _Chem. Eur. J._, 9, 2895 (2003). * Y. Furusho, T. Oku, G. A.

Rajkumar, and T. Takata, _Chem. Lett._, 33, 52 (2004). * For example, Y. Geerts, D. Muscat, and K. Müllen, _Macromol. Chem. Phys._, 196, 3425 (1995). * S. J. Rowan, S. J. Cantrill, J. F.

Stoddart, A. J. P. White, and D. J. Williams, _Org. Lett._, 2, 759 (2000). * M. C. Jiménez, C. Dietrich-Buchecker, and J.-P. Sauvage, _Angew. Chem., Int. Ed._, 39, 3284 (2000). * T. Hoshino,

M. Miyauchi, Y. Kawaguchi, H. Yamaguchi, and A. Harada, _J. Am. Chem. Soc._, 122, 9876 (2000). * T. Fujimoto, Y. Sakata, and T. Kaneda, _Chem. Comunn._, 2143 (2000). * H. Onagi, C. J.

Easton, and S. F. Lincoln, _Org. Lett._, 3, 1041 (2001). * T. Oku, Y. Furusho, and T. Takata, _J. Polym. Sci., Part A: Polym. Chem._, 41, 119 (2003). * N. Yamaguchi and H. W. Gibson, _Angew.

Chem., Int. Ed._, 38, 143 (1999). * Y. Sohgawa, H. Fujimori, J. Shoji, Y. Furusho, N. Kihara, and T. Takata, _Chem. Lett._, 774 (2001). * W. J. Lee and G. M. Whiteside, _J. Org. Chem._, 58,

642 (1993) and references cited therein. * C. Gong and H. W. Gibson, _Macromol. Chem. Phys._, 199, 1801 (1998). * Y. Delaviz and H. W. Gibson, _Macromolecules_, 25, 4859 (1992). * H. W.

Gibson, D. S. Nagveker, J. Powell, C. Gong, and W. S. Bryant, _Tetrahedron_, 53, 15197 (1997). * C. Gong and H. W. Gibson, _J. Am. Chem. Soc._, 119, 8585 (1997). * C. Gong and H. W. Gibson,

_J. Am. Chem. Soc._, 119, 5862 (1997). * A. Zada, Y. Avny, and A. Zilkha, _Eur. Polym. J._, 35, 1159 (1999). * A. Zada, Y. Avny, and A. Zilkha, _Eur. Polym. J._, 36, 351 (2000). * A. Zada,

Y. Avny, and A. Zilkha, _Eur. Polym. J._, 36, 359 (2000). * H. Oike, T. Mouri, and Y. Tezuka, _Macromolecules_, 34, 6229 (2001). * M. Kubo, T. Hibino, M. Tamura, T. Uno, and T. Itoh,

_Macromolecules_, 35, 5816 (2002). * Y. Okumura and K. Ito, _Adv. Mater._, 13, 485 (2001). * J. Araki, C. Zhao, and K. Ito, _Macromolecules_, 38, 7524 (2005). * J. Watanabe, T. Ooya, and N.

Yui, _J. Biomater. Sci., Polym. Ed._, 10, 1275 (1999). * J. Watanabe, T. Ooya, K. D. Park, Y. H. Kim, and N. Yui, _J. Biomater. Sci., Polym. Ed._, 11, 1333 (2000). * T. Ichi, J. Watanabe, T.

Ooya, and N. Yui, _Biomacromolecules_, 2, 204 (2001). * T. Oku, Y. Furusho, and T. Takata, _Angew. Chem., Int. Ed._, 43, 966 (2004). * N. Kihara, K. Hinoue, and T. Takata, _Macromolecules_,

38, 223 (2005). * L. D. Melton and K. N. Slessor, _Carbohydr. Res._, 18, 29 (1971). * M. Tanaka, Y. Kawaguchi, T. Niinae, and T. Shono, _J. Chromotogr._, 314, 193 (1984). * T. Kaneda, T.

Fujimoto, J. Goto, K. Asano, Y. Yasufuku, J. H. Jung, C. Hosono, and Y. Sakata, _Chem. Lett._, 5, 514 (2002). * T. Endo, T. Suzuki, F. Sanda, and T. Takata, _Macromolecules_, 29, 3315

(1996). * T. Endo, T. Suzuki, F. Sanda, and T. Takata, _Macromolecules_, 29, 4819 (1996). * T. Endo, T. Suzuki, F. Sanda, and T. Takata, _Bull. Chem. Soc. Jpn._, 70, 1205 (1997). * S.

Chikaoka, T. Takata, and T. Endo, _J. Polym. Sci., Part A: Polym. Chem._, 28, 3103 (1990). * S. Chikaoka, T. Takata, and T. Endo, _Macromolecules_, 24, 331 (1991). * S. Chikaoka, T. Takata,

and T. Endo, _Macromolecules_, 24, 6557 (1991). * N. Watanabe, Y. Ikari, N. Kihara, and T. Takata, _Macromolecules_, 37, 6663 (2004). * K. Endo, T. Shiroi, N. Murata, G. Kojima, and T.

Yamanaka, _Macromolecules_, 37, 3143 (2004). Download references AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Organic and Polymeric Materials, Tokyo Institute of Technology,

2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8552, Japan Toshikazu Takata Authors * Toshikazu Takata View author publications You can also search for this author inPubMed Google Scholar

CORRESPONDING AUTHOR Correspondence to Toshikazu Takata. RIGHTS AND PERMISSIONS Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Takata, T. Polyrotaxane and Polyrotaxane

Network: Supramolecular Architectures Based on the Concept of Dynamic Covalent Bond Chemistry. _Polym J_ 38, 1–20 (2006). https://doi.org/10.1295/polymj.38.1 Download citation * Received: 02

November 2005 * Accepted: 07 November 2005 * Published: 15 October 2006 * Issue Date: 01 January 2006 * DOI: https://doi.org/10.1295/polymj.38.1 SHARE THIS ARTICLE Anyone you share the

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Nature SharedIt content-sharing initiative KEYWORDS * Rotaxane * Polyrotaxane * Polyrotaxane Network * Gel * Interlocked Polymer