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ABSTRACT A novel design and facile synthesis process for carbon based hybrid materials, i.e., cobalt monoxide (CoO)-doped graphitic porous carbon microspheres (Co-GPCMs), have been

developed. With the synthesis strategy, the mixture of cobalt gluconate, α-cyclodextrin and poly (ethylene oxide)106-poly (propylene oxide)70-poly (ethylene oxide)106 is treated

hydrothermally, followed by pyrolysis in argon. The resultant Co-GPCMs exhibits a porous carbon matrix with localized graphitic structure while CoO nanodots are embedded in the carbon frame.

Thus, the Co-GPCMs effectively combine the electric double-layer capacitance and pseudo-capacitance when used as the electrode in supercapacitor, which lead to a higher operation voltage

(1.6 V) and give rise to a significantly higher energy density. This study provides a new research strategy for electrode materials in high energy density supercapacitors. SIMILAR CONTENT

BEING VIEWED BY OTHERS RAPID COLD PLASMA SYNTHESIS OF COBALT METAL–ORGANIC FRAMEWORK/REDUCED GRAPHENE OXIDE NANOCOMPOSITES FOR USE AS SUPERCAPACITOR ELECTRODES Article Open access 13

September 2023 SYNTHESIS OF POLYPYRROLE/NITROGEN-DOPED POROUS CARBON MATRIX COMPOSITE AS THE ELECTRODE MATERIAL FOR SUPERCAPACITORS Article Open access 21 September 2020 IN SITU ACTIVATION

GRAPHITIZATION TO FABRICATE HIERARCHICAL POROUS GRAPHITIC CARBON FOR SUPERCAPACITOR Article Open access 25 March 2021 INTRODUCTION Supercapacitors, which are also named as ultracapacitors or

electrochemical capacitors, have attracted considerable attention due to their high power density, low cost and high efficiency1,2,3. In recent years, they have been extensively

investigated for energy storage, in attempts to improve their energy density and overall performance1,2,3. In general, there are two main types of supercapacitors on the basis of energy

storage process1,2,3. The first type is the electric double-layer supercapacitors (EDLS), where the capacitance is generated from the electrostatic charges which are stored at the interface

between electrode and electrolyte4. In the development of electrode materials with high surface specific area and controlled porosity for EDLS, carbon-based materials, such as activated

carbon, carbon nanotubes, graphene, carbon film, carbon foam and mesoporous carbon, have been investigated5,6,7,8,9,10. They are among the most promising materials owing to their desirable

physical and chemical behaviour and processing ability, including tuneable morphologies, controllable porosity, relatively inert surface electrochemistry, high electrical conductivity and

low manufacturing cost5,6,7,8,9,10,11. Since there is no electrochemical reaction between the electrode of carbon and electrolyte, the performance of EDLS is mainly dependent on the

available surface area, pore size distribution, connectivity and electrical conductivity12. In contrast, pseudo-supercapacitors are the other type of supercapacitors, which are built on the

basis of the fast and reversible faradaic reactions between electrode materials and electrolytes13. There is faradaic current across the supercapacitor cell during the reversal processes of

charging and discharging, which not only increases the specific capacitance but also extends the operation voltage of the supercapacitor14. Thus, transition metal (such as ruthenium,

manganese, vanadium, tin, iron, nickel and cobalt) oxides and hydroxides with pseudo-capacitive behaviour are of great interest for the application as electrode materials in

pseudo-supercapacitors15,16,17,18,19,20,21,22,23,24,25. Although in recent years, a large number of studies have been made with the development of both types of supercapacitors with both

theoretical understanding and practical fabrication made, the main challenges are still the low energy density and poor overall performance, which have to be tackled in order to widen the

applications of supercapacitors1,2,3,26. In order to improve the desperately wanted energy density, an effective approach is to increase the capacitance and operation voltage, since the

energy density (_E_) is in theory related to both parameters, _E_ = 0.5_CV_2, where _C_ (in farads) and _V_ (in volts) are the capacitance and operation voltage, respectively3,27. Therefore,

electrode materials with the desirable physical and electrochemical performances are the key factors in leading to high energy density for supercapacitors28. In particular, it would be of

interest to effectively combine the double-layer capacitance and pseudo-capacitance by developing a hybrid type of electrode materials, where electric double-layers and faradaic capacitance

can be realized concurrently to contribute to the high energy density and better overall performance29. Herein, we report a novel design and facile synthesis process for carbon based hybrid

materials, i.e., cobalt monoxide (CoO)-doped graphitic porous carbon microspheres (Co-GPCMs), as a promising electrode material in supercapacitors showing high energy density. As shown in

Fig. 1, the desirable carbon microspheres would contain both nanopores (1–2 nm) and mesopores (5–50 nm), where the carbon wall exhibits the graphitic structure. For energy storage by EDLS,

the porous structure of carbon microspheres would provide the wanted interfaces for electrostatic charge accumulation, while the graphitic carbon wall could enhance the electric

conductivity30. Moreover, CoO as a transitional metal oxide offers the potential of pseudo-supercapacitors25. The hybrid electrode is expected to be electrochemically active, enabling the

reaction with the electrolyte by fast and reversible faradaic reactions to enhance the operation voltage31. This would effectively combine the EDLS of carbon and pseudo-supercapacitors of

CoO, leading to an improvement in energy density. The designed Co-GPCMs are prepared by a facile synthesis process, conducted under controlled hydrothermal condition, where the mixture of

cobalt gluconate (Co-gluconate), α-cyclodextrin (α-CD) and poly (ethylene oxide)106-poly (propylene oxide)70-poly (ethylene oxide)106 (F127) is treated hydrothermally, followed by pyrolysis

process in argon (Ar). As detailed in the results and discussion below, the resultant Co-GPCMs is demonstrated promising as an electrode material in supercapacitors. RESULTS The scanning

electron microscopy (SEM) and transmission electron microscopy (TEM) images of the microspheres derived from the hydrothermal treatment of Co-gluconate and α-CD in the presence of F127 are

shown in Fig. 2 (a) and (b), where one can see their morphologies and inner structures. The hydrothermal treatment of Co-gluconate and α-CD in the presence of F127 at 200°C for 6 h lead to a

spherical structure with average size of 1464 nm. In addition, from the TEM image shown in Fig. 2 (b), the carbon microspheres are solid without cavity inside the carbon frame. In contrast,

upon pyrolysis treatment of the as-prepared carbon microspheres in Ar gas at 900°C for 3 h, a graphitic porous carbon structure is established for Co-GPCMs, as shown in Fig. 2 (c) and (d).

From the SEM image in Fig. 2 (c), the Co-GPCMs are spherical in morphology with an average size of ~1200 nm. Moreover, the surface of these Co-GPCMs appears rough, which is apparently due to

the decomposition of F127 by pyrolysis32. Indeed the decomposition of F127 by pyrolysis treatment is confirmed by the shrinkage in the average microsphere size, which is indicated by the

change in size distribution histogram before and after pyrolysis (see Supplementary Fig. S1 online). As a result, upon pyrolysis, there is a visible porous structure established in the

carbon frame, which is further confirmed by SEM and TEM images showing their fracture surface (inset in Fig. 2 (c) and (d)). In addition, the TEM image shown in Supplementary Fig. S2

confirms the presence of pores of varying sizes inside the Co-GPCMs. As shown in Fig. 2 (e), which is a high resolution TEM image of an individual pore inside Co-GPCMs, it appears to consist

of crystallized carbon, which is in close match with the (002) lattice spacing of disordered graphite33. In addition, as shown in Fig. 2 (d), the black dots embedded in the carbon spheres

are Co in composition, which is further confirmed by scanning TEM-energy dispersive X-ray spectroscopy (STEM-EDX) line analysis and element mapping as shown in Fig. 3. As shown in Fig. 3,

the carbon microspheres contain rather uniformly distributed Co element, as confirmed by the STEM-EDX line analysis (Fig. 3 (a)) and the corresponding Co element mapping (Fig. 3 (d)). At the

hydrothermal temperature of 200°C, α-CD is converted to carbon while the dissolved Co salt is wrapped in the carbon matrix, which is assisted by the hydrogen bonding between Co-gluconate

with α-CD and F12734. Upon pyrolysis, the soft template of F127 is decomposed to generate a porous structure inside the Co-GPCMs. The structure change of F127 is demonstrated by Fourier

transform infrared (FTIR) spectrometry (see Supplementary Fig. S3 online), where the characteristic FTIR peaks of F127 have disappeared in the FTIR spectrum of Co-GPCMs. In addition, since

Co-gluconate is an inorganic salt, which would be converted to Co-based nanodots at the high temperature of pyrolysis treatment, Co is known to play a key function of acting as a catalyst

for forming graphitic carbon35. The conversion of Co-gluconate to Co-based nanodots distributed in the Co-GPCMs is confirmed by the STEM-EDX line analysis (Fig. 3 (e)) and the corresponding

Co element mapping (Fig. 3 (h)). To further understand the crystal structure and porous distribution in Co-GPCMs, X-ray diffraction (XRD), Raman spectrum and Brunauer-Emmett-Teller (BET)

analysis are conducted, which are shown in Fig. 4. From the XRD phase analysis, which is shown in Fig. 4 (a), crystallites of both carbon and Co-based nanodots in Co-GPCMs can be identified.

Obviously, Fig. 4 (a) shows a typical characteristic XRD pattern of graphitic carbon (labelled by + in Fig. 4 (a)), which exhibits peaks at 2θ of 26°, 44°, 54° and 77°. These peaks are

assigned to the (002), (101), (004) and (110) planes of the graphitic carbon frame, respectively (JCPDS file number 41-1487)36. In addition, the presence of the sharp (002) diffraction peak

indicates that the Co-GPCMs exhibits a highly ordered graphitic structure, which corresponds well to the result of TEM studies in Fig. 236. The crystalline phase of Co-based nanodots is

indentified by the XRD peaks (labelled by * in Fig. 4 (a)) at 2θ angles of 37°, 42° and 62°, which represent the (111), (200) and (220) diffractions of CoO (JCPDS file number 43-1004)37. The

amount of CoO retained in Co-GPCMs is measured to be 4.2 wt.% by Inductively Coupled Plasma (ICP) analysis. Since there is a rather small amount of CoO in the Co-GPCMs, which is further

confirmed by the STEM-EDX line analysis (Fig. 3 (e)) and the EDX spectrum (see Supplementary Fig. S4 online), the presence of CoO nanodots is not as obvious as that of the graphitic carbon

frame. The phase structures of graphitic carbon and CoO nanodots embedded in the microspheres are further studied by using Raman spectrometer, the result of which is shown in Fig. 4 (b). As

labelled by + in Fig. 4 (b), the peaks centred at 1338, 1593, 2694 and 2922 cm−1 are the representative bands of graphitic carbon38. Among them, the three intense peaks at 1338, 1593 and

2694 cm−1 are assigned to the defect, the breath mode of graphite lattice and the 2nd order band of graphite, respectively39. Moreover, the peak centred at 2694 cm−1 indicates the presence

of sp3 C-H and C-H2 groups in the Co-GPCMs40. In addition, the presence of CoO nanodots in Co-GPCMs is further confirmed by the corresponding peak at 468 and 672 cm−1 (labelled by * in Fig.

4 (b))41. Thus, the result of Raman spectroscopy agrees well with the TEM and XRD studies. By comparison, in the Raman spectra and XRD traces of the carbon microspheres synthesized by

hydrothermal treatment of Co-gluconate and α-CD in the presence of F127 at 200°C for 6 h (see Supplementary Fig. S5 online), there is no clear indication for the characteristic peaks of

ordered graphite and crystallized CoO. As shown in Fig. S5 (a), the Raman spectra of the carbon microspheres before pyrolysis treatment exhibits the characteristic peaks at 1389 and 1583 

cm−1. The peak at 1583 cm−1 is broader than the typical G band of disordered graphite, indicating that there are aromatic and olefinic molecules co-existing in the carbon microspheres32. The

existence of sp2 carbon atoms pairs is demonstrated by the broad XRD peak at 26° in Fig. S5 (b). During the pyrolysis, graphitic carbon is formed from these aromatic carbon structures by

the catalyst effect of Co element inside the carbon microspheres35. Since CoO is formed when the Co-based compound is annealed at 900°C, the existence of CoO in the graphitic porous carbon

frame is apparently due to the conversion of Co-gluconate at the pyrolysis temperature as O is present in the α-CD and F12737. The porous structure of Co-GPCMs is further studied by BET

measurement using nitrogen (N2). As shown in Fig. S5 (c), there is negligible N2 adsorption occurring over the relative pressure range (_P_/_P_0) of 0–0.9 indicating a nonporous character

for the carbon microspheres before pyrolysis, where the specific surface area calculated from the BET result is quite small, i.e., 7.2 m2g−1. In contrast, the porous structure of the carbon

frame of Co-GPCMs generated by pyrolysis treatment is demonstrated, as shown in Fig. 4 (c) and (d). The N2 adsorption/desorption isotherms for Co-GPCMs (Fig. 4 (c)) demonstrate that both

nanopores and mesopores are present in the Co-GPCMs with a total BET surface area of 381 m2g−1. As shown in the N2 adsorption curve, the linear increase of N2 uptake at low pressure range,

which is _P_/_P_0 = 0.06–0.2, indicates a monolayer gas adsorption inside the pores32,42. When approaching the full filling of pores, the adsorption curve of N2 shows a near plateau at

_P_/_P_0 = 0.2–0.9, which suggests the presence of nanopores (60% in t-plot pore volume) together with some mesopores. This is further confirmed by the pore size distribution peaked at 2.5 

nm (Fig. 4 (d)) with a differential pore volume of 0.11 cm3g−1, which is calculated by the nonlocal density functional theory (NLDFT) method. Moreover, the sharp increase in the N2

adsorption curve at _P_/_P_0 = 0.9–1.0 corresponds to the inter-particle voids32,42. The aggregates of platy particles make the non-closing hysteresis loops at _P_/_P_0 = 0.4–1.0 while the

ink-bottle type of pores leads the sudden closure at _P_/_P_0 = 0.4 in the N2 desorption branch43. DISCUSSION On the basis of the characterization results of Co-GPCMs, there are both

nanopores and mesopores inside the carbon microspheres with localized graphitic structure, which would benefit the specific surface area and electrical conductivity. In addition, the

presence of CoO nanodots in the carbon matrix could give rise to pseudo-capacitance. The performance of Co-GPCMs as electrode materials in supercapacitors is evaluated by cyclic voltammetry

(CV) and galvanostatic charge-discharge measurement (Fig. 5) in 6 M potassium hydroxide (KOH) aqueous electrolyte. As shown in Fig. 5 (a) and (b), the quasi-rectangular voltammogram shape

and symmetric linear galvanostatic charge-discharge profile show the typical electrochemical behaviour of carbon-based materials within the operation voltage of −1.2–0 V, which implies that

the Co-GPCMs exhibits excellent capacitive behaviour and electrochemical reversibility for EDLS36,44. In addition, the presence of pseudo-capacitance is demonstrated in Fig. 5 (c) and (d)

with a typical CV and galvanostatic charge-discharge shape for CoO, which indicates the faradaic reactions, and , taking place within the operation voltage of 0–0.4 V25. Further studies with

the working electrode made of Co-GPCMs within the operation voltage of −1.2–0.4 V, which is shown in Fig. 5 (e) and (f), show that the supercapacitor working electrode exhibits both

electric double-layer capacitance and pseudo-capacitance in 6 M KOH aqueous electrolyte. Thus, the overall operation voltage of the supercapacitor working electrode made of Co-GPCMs is 1.6 V

in 6 M KOH aqueous electrolyte, which is higher than the typical porous carbon and Co based materials1,2,3,25,45. Moreover, the specific capacitance for the working electrode made of

Co-GPCMs (Fig. 5 (g)) is 194, 92 and 191 Fg−1 within the operation voltage of −1.2–0, 0–0.4 and −1.2–0.4 V, respectively, at the current density of 0.1 Ag−1. These results indicate that the

overall specific capacitance of Co-GPCMs is at least comparable to the best porous carbon materials, while doping CoO nanodots into the carbon matrix gives rise to an extension of operation

voltage. For comparison purpose, a working electrode is made of carbon spheres synthesized from α-CD and F127 without Co-gluconate by following the same experimental procedure (see

Supplementary Fig. S6 and S7 online). As shown in Fig. S6, when Co-gluconate is not added, the carbon spheres do not contain any graphitic porous structure. The electrochemical performance

is expectedly similar with that of a conventional carbon material (see Supplementary Fig. S7 online), where quasi-rectangular shape of voltammogram (see Supplementary Fig. S7 (a) (b) and (c)

online) and symmetric linear galvanostatic charge-discharge profile (see Supplementary Fig. S7 (c) online) are shown. The operation voltage is only from −1.0 to 0 V, within which the

specific capacitance is 188 and 148 Fg−1 at the current density of 0.1 Ag−1 and scan rate of 1 mVs−1, respectively (see Supplementary Fig. S7 (d) and (e) online). In addition, the

establishment of graphitic carbon structure in Co-GPCMs provides a higher conductivity, which is confirmed by the internal resistance calculated from the plot of IR drop (see Supplementary

Fig. S8 online). The equivalent series resistance (ESR) of Co-GPCMs is calculated to be 0.03069 Ωg. The specific capacitance of the working electrode made of Co-GPCMs could retain 40% with

the increase in current density from 0.1 to 10 Ag−1 (Fig. 5 (g)), while the shape of CV is still maintained with the increase in scan rate from 1 to 100 mVs−1 (see Supplementary Fig. S9

online). Furthermore, from Fig. S9 (a)–(c), the specific capacitance of the working electrode made of Co-GPCMs is seen to retain 55% with the increase in scan rate, which shows a good rate

capability. This highlights that the working electrode would be suitable for fast charge-discharge and high scan rate operations within the potential window of 1.6 V30,46. The high operation

voltage (1.6 V) of the working electrode made of Co-GPCMs could therefore generate an improved high energy density for supercapacitors. In order to understand the performance for energy

density, the ragone plot (Fig. 5 (h)) is calculated based on the CV and galvanostatic charge-discharge results, where one sees an energy density of 62 Whkg−1 at a power density of 152 Wkg−1.

It maintains 29 Whkg−1 at a power density of 1.6 kWkg−1 in the three electrode system. With a symmetric two working electrode system, the energy density is 5.6 Whkg−1 at a power density of

152 Wkg−1 while maintaining 1.0 Whkg−1 at a power density of 1.6 kWkg−1. In contrast, when there was no CoO doping in the carbon spheres, the overall energy density was much lower than that

of Co-GPCMs (see Supplementary Fig. S10 online). In addition, the working electrode made of Co-GPCMs demonstrates similar electrochemical behaviour by using either Ag/AgCl or saturated

calomel electrode (SCE) reference electrode (see Supplementary Fig. S11 online). As shown in Fig. S11, the supercapacitor working electrode shows both electric double-layer capacitance and

pseudo-capacitance performance by using SCE as the reference electrode. The specific capacitance for the working electrode made of Co-GPCMs is 210, 97 and 210 Fg−1 within the operation

voltage of −1.2–0, 0–0.4 and −1.2–0.4 V, respectively, at the current density of 0.1 Ag−1 by using SCE as the reference electrode. The working electrode could retain 47% of the specific

capacitance with the increase in current density from 0.1 to 10 Ag−1, while the CV shape is still maintained with the increase in scan rate from 1 to 100 mVs−1. 54% of the specific

capacitance could be retained with the increase in scan rate, demonstrating a good rate capability of the working electrode by using SCE as the reference electrode. From the CV and

galvanostatic charge-discharge results in Fig. S11, one can see an energy density of 68 Whkg−1 at a power density of 152 Wkg−1. It maintains an energy density of 36 Whkg−1 at the power

density of 1.6 kWkg−1 in the SCE reference electrode system. These data demonstrate the excellent capacitive performance of Co-GPCMs with the aqueous electrolyte. Concerning the cyclic

retention, the working electrode made of Co-GPCMs could retain 90% of the specific capacitance after 1500 cycles of measurement. It could retain 22% after 5000 cycles of measurements (see

Supplementary Fig. S12 online), the exact cause for which is subject to further investigation. In summary, a novel design and facile synthesis process have been developed for hybrid-type

carbon microspheres, which exhibit a graphitic porous structure. The Co-GPCMs are successfully realized by the hydrothermal treatment of Co-gluconate and α-CD in the presence of F127,

followed by pyrolysis at high temperature in Ar. The Co-GPCMs consists of a porous carbon matrix with localized graphitic structure while CoO nanodots are embedded in the carbon frame. The

hybrid structure is aimed at effectively combining the electric double-layer capacitance and pseudo-capacitance, which has been successfully demonstrated when used as the electrode material

in supercapacitors. The combination of EDLS, which is generated by the porous graphitic carbon and pseudo-supercapacitors, which is generated by CoO, leads to a high operation voltage (1.6 

V), which gives rise to a high energy density. METHODS MATERIALS Co-gluconate and F127 were purchased from Sigma-Aldrich Company. α-CD was purchased from Tokyo Chemical Industry Company. All

chemicals were used without further purification. For fabrication of working electrode, carbon black was purchased from CABOT Company (VULCAN®XC72). Polytetrafluoroethylene was purchased

from Sigma-Aldrich Company (60 wt.% in H2O). Ni foam was purchased from LATECH Company (>99% Ni, 90–98% volumetric porosity). SYNTHESIS OF CO-GPCMS Co-GPCMs were synthesised via

hydrothermal treatment route followed by pyrolysis. Firstly, 300 mg F127 was dissolved in 20 mL deionized (DI) water. 49 mg of Co-gluconate dissolved in 10 mL DI water was then injected into

the solution of F127 under stirring at 700 rpm. After that, 600 mg of α-CD dissolved in 10 mL DI water was injected into the mixed solution of F127 and Co-gluconate under stirring at 700 

rpm. The mixed solution was further stirred overnight and then transferred into a Teflon sealed autoclave tube. Upon hydrothermal treatment at 200°C for 6 h, the clear solution turned into

black in appearance. The black product was then collected by centrifugation at 9000 rpm for 30 min and then washed by DI water three times. After washing, the black precipitates were

re-dispersed in DI water and freeze dried for two days to obtain the black powder. Finally, the dried powder was further pyrolyzed in a tube furnace at 900°C for 3 h under Ar gas protection.

CHARACTERIZATION The morphology and phase structure of the products were studied by using SEM (ZEISS SUPRA 40) and TEM (CM 300 FEG-Philips). To study their fracture surface, the

as-synthesized Co-GPCMs powders were frozen by liquid N2 and grinded to get fracture surface. The STEM-EDX line analysis and elemental mapping were conducted by using TEM (JEOL 2100). FTIR

spectra were acquired by using Perkin Elmer FT-IR 2000 spectrometer, where the sample was prepared by pressing the mixture of the sample powder and potassium bromide into a thin disk. XRD

phase analysis was conducted by using Bruker D8 XRD which is equipped with Cu Kα radiation (λ = 0.15418 nm). Raman spectra were acquired by using RENISHAW Raman Microscope with 514 nm laser

radiation source. N2 adsorption and desorption isotherms were measured at −196°C by using a Micromeritics ASAP 2020 system. In addition, the surface area was determined by the BET method and

the pore size distribution was calculated using the NLDFT method. The amount of CoO in carbon spheres was determined by ICP analysis using Perkin Elmer Dual-view Optima 5300 DV ICP-OES

system. ELECTROCHEMICAL PERFORMANCE EVALUATION OF CO-GPCMS Electrochemical performances of the Co-GPCMs as supercapacitor working electrode materials were investigated using a Solartron

Electrochemical System SI 1287. The working electrode was fabricated by coating the viscous slurry of Co-GPCMs (80 wt.%), carbon black (10 wt.%) and polytetrafluoroethylene (10 wt.%) in

ethanol onto a Ni foam of 2.25 cm2 in area and 1 mm in thickness. After drying in a vacuum oven at 120°C for 12 h, the coated Ni foam was uniaxially pressed at a pressure of 49 MPa to

enhance the adhesion between the active materials (18.7 mg) and the Ni foam. A series of electrochemical tests were made with the working electrode, including the CV and galvanostatic

charge-discharge by using 6 M KOH aqueous solution as the electrolyte, which was purged with N2, within the operation voltage of −1.2–0, 0–0.4 and −1.2–0.4 V. The fabrication procedure of

working electrode for carbon spheres made from α-CD and F127 is the same as that described above. In the three electrode system, Pt foil was used as the counter electrode, while Ag/AgCl or

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ACKNOWLEDGEMENTS This work is supported by the Agency for Science, Technology and Research (A-Star, Singapore), Grant number: 1121202013, conducted at the National University of Singapore.

AUTHOR INFORMATION AUTHORS AND AFFILIATIONS * Department of Materials Science and Engineering, National University of Singapore, Blk EA, #03-09, 9 Engineering Drive 1, 117576, Singapore

Zheng-Chun Yang, Chun-Hua Tang, Yu Zhang, Hao Gong & John Wang * Institute of Materials Research and Engineering (IMRE), The Agency for Science, Technology and Research (A-STAR),

Research Link, 3, 117602, Singapore Xu Li Authors * Zheng-Chun Yang View author publications You can also search for this author inPubMed Google Scholar * Chun-Hua Tang View author

publications You can also search for this author inPubMed Google Scholar * Yu Zhang View author publications You can also search for this author inPubMed Google Scholar * Hao Gong View

author publications You can also search for this author inPubMed Google Scholar * Xu Li View author publications You can also search for this author inPubMed Google Scholar * John Wang View

author publications You can also search for this author inPubMed Google Scholar CONTRIBUTIONS Z.Y. designed and carried out the experiments. C.T. and H.G. supervised the electrochemical

performance characterization. Y.Z. contributed the BET analysis. X.L. and J.W. supervised the project. Z.Y. wrote the manuscript and all authors discussed the results and contributed to

revisions. ETHICS DECLARATIONS COMPETING INTERESTS The authors declare no competing financial interests. ELECTRONIC SUPPLEMENTARY MATERIAL SUPPLEMENTARY INFORMATION Supporting information 1

RIGHTS AND PERMISSIONS This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported License. To view a copy of this license, visit

http://creativecommons.org/licenses/by-nc-nd/3.0/ Reprints and permissions ABOUT THIS ARTICLE CITE THIS ARTICLE Yang, ZC., Tang, CH., Zhang, Y. _et al._ Cobalt monoxide-doped porous

graphitic carbon microspheres for supercapacitor application. _Sci Rep_ 3, 2925 (2013). https://doi.org/10.1038/srep02925 Download citation * Received: 31 May 2013 * Accepted: 24 September

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